The answer is in fact no in general, as shown by Kahn and Kalai [KaKa93], who proved that it is false for $n>2014$. The current smallest $n$ where Borsuk's conjecture is known to be false is $n=64$, a result of Brouwer and Jenrich [BrJe14].
If $\alpha(n)$ is the smallest number of pieces of diameter $<1$ required (so Borsuk's original conjecture was that $\alpha(n)=n+1$) then Kahn and Kalai's construction shows that $\alpha(n)\geq (1.2)^{\sqrt{n}}$. The best upper bound, due to Schramm [Sc88], is that \[\alpha(n) \leq ((3/2)^{1/2}+o(1))^{n}.\]