SOLVED
How large can a union-free collection $\mathcal{F}$ of subsets of $[n]$ be? By union-free we mean there are no solutions to $A\cup B=C$ with distinct $A,B,C\in \mathcal{F}$. Must $\lvert \mathcal{F}\rvert =o(2^n)$? Perhaps even
\[\lvert \mathcal{F}\rvert <(1+o(1))\binom{n}{\lfloor n/2\rfloor}?\]
The estimate $\lvert \mathcal{F}\rvert=o(2^n)$ implies that if $A\subset \mathbb{N}$ is a set of positive density then there are infinitely many distinct $a,b,c\in A$ such that $[a,b]=c$ (i.e.
[487]).
Solved by Kleitman [Kl71], who proved
\[\lvert \mathcal{F}\rvert <(1+o(1))\binom{n}{\lfloor n/2\rfloor}.\]