Taking all integers $\equiv 1\pmod{3}$ shows that $\lvert A\rvert\geq N/3$ is possible. This can be improved to $\tfrac{11}{32}N$ by taking all integers $\equiv 1,5,9,13,14,17,21,25,26,29,30\pmod{32}$, as observed by Massias.

Lagarias, Odlyzko, and Shearer [LOS83] proved this is sharp for the modular version of the problem; that is, if $A\subseteq \mathbb{Z}/N\mathbb{Z}$ is such that $A+A$ contains no squares then $\lvert A\rvert\leq \tfrac{11}{32}N$. They also prove the general upper bound of $\lvert A\rvert\leq 0.475N$ for the integer problem.

In fact $\frac{11}{32}$ is sharp in general, as shown by Khalfalah, Lodha, and Szemerédi [KLS02], who proved that the maximal such $A$ satisfies $\lvert A\rvert\leq (\tfrac{11}{32}+o(1))N$.

See also [439] and [587].